Today, petrochemical compounds and rare metals such as Platinum and Iridium are usually used to produce semiconductors for optoelectronics, such as organic LEDs for super-thin TV and mobile phone screens. Physicists at Umeå University in collaboration with researchers in Denmark and China show a more sustainable alternative. By pressure-cooking birch leaves picked on the Umeå University campus, they have produced a nano-sized carbon particle with desired optical properties. The results have been published in the Green Chemistry.
“The essence of our research is to harness nearby renewable resources for producing organic semiconductor materials” says Jia Wang, research fellow at the Department of Physics, Umeå University, and one of the authors of the study.
Organic semiconductors are one of the most important functional materials in optoelectronic applications. One example is the organic light-emitting diodes, OLEDs, which enable ultra-thin and bright TV and mobile phone screens. Sharply increasing demand for this advanced technology is driving massive production of organic semiconductor materials. Unfortunately, these semiconductors are currently produced mainly from petrochemical compounds and rare elements, obtained through environmentally harmful mining. Moreover, these materials often contain so-called ‘critical raw materials’ that are in short supply, such as Platinum, Indium and Phosphorus.
From a sustainability point of view, it would be ideal if we can use biomass from plants, animals and waste to produce organic semiconductor materials. These starting materials are renewable and abundantly available. Research fellow Jia Wang and her colleagues at the Department of Physics, together with international partners, have succeeded in producing such a bio-based semiconductor material.
Birch leaves in pressure cooker
The synthesis process is simple: they picked birch leaves on the Umeå campus and cooked them in a pressure cooker. That produced a kind of ‘carbon dots’ about two nanometers in size, which emit a narrow-band, deep red light when dissolved in ethanol. Some of the optical properties of these birch leaf carbon dots are comparable to commercial quantum dots currently used in semiconductor materials, but unlike them, they contain no heavy metals or critical raw materials.
Carbon dot solutions emit various luminescence under UV illumination. All carbon dots in the photograph are synthesized in Jia’s research lab. Photo: Jia Wang
”It is important to note that our method is not limited to birch leaves” explains Jia Wang. “We tested different plant leaves with the same pressure cooking method, and all of them produced similar red-emitting carbon dots. This versatility suggests that the transformation process can be used in different locations.”
Using the carbon dots in a light-emitting electrochemical cell device, the researchers were able to show that the brightness generated was 100 cd/m2, which is comparable to the light intensity from a computer screen.
”This result shows that it is possible to transition from depleting petroleum compounds to regenerating biomass as a raw material for organic semiconductors” says Jia Wang.
She emphasises the broader potential of carbon dots beyond just light-emitting devices.
“Carbon dots are promising across various applications, from bioimaging and sensing to anti-counterfeiting. We’re open to collaborations and eager to explore more exciting uses for these emissive and sustainable carbon dots” says Jia Wang.
About the study
Shi Tang, Yongfeng Liu, Henry Opoku, Märta Gregorsson, Peijuan Zhang, Etienne Auroux, Dongfeng Dang, Anja-Verena Mudring, Thomas Wågberg, Ludvig Edman, Jia Wang, Fluorescent carbon dots from birch leaves for sustainable electroluminescent devices, Green Chemistry, Royal Society of Chemistry, November 2023, DOI: 10.1039/d3gc03827k
Jia Wang, research fellow, Department of Physics, Umeå university Phone: +46 90 786 69 03 Email: firstname.lastname@example.org
Umeå University Umeå University is one of Sweden’s largest institutions of higher education with over 37,000 students and 4,300 faculty and staff. The university is home to a wide range of high-quality education programmes and world-class research in a number of fields. Umeå University was also where the revolutionary gene-editing tool CRISPR-Cas9 was discovered that has been awarded the Nobel Prize in Chemistry.
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